Bis(dihydrogen phosphato-O)[(1SR, 4SR, -8RS, 11RS)-1,4,8,11-tetraazacyclotetradecane-κ4N]nickel(II )
Identifieur interne : 000D51 ( Main/Exploration ); précédent : 000D50; suivant : 000D52Bis(dihydrogen phosphato-O)[(1SR, 4SR, -8RS, 11RS)-1,4,8,11-tetraazacyclotetradecane-κ4N]nickel(II )
Auteurs : SAOUSSEN NAMOUCHI CHERNI [Tunisie] ; A. Driss [Tunisie] ; M. El Maaoui [Tunisie] ; Tahar Jouini [Tunisie]Source :
- Acta crystallographica. Section C, Crystal structure communications [ 0108-2701 ] ; 1998.
Descripteurs français
- Pascal (Inist)
- Etude expérimentale, Diffraction RX, Structure cristalline, Structure moléculaire, Nickel II Complexe, Liaison hydrogène, Coordinat organique, Composé crown azote, Analogue, Hétérocycle azote, Macrocycle, Complexe aniono, Complexe phosphato, 6166F, Complexe dihydrogénophosphato, 1,4,8,11-Tétraazacyclotétradécane.
English descriptors
- KwdEn :
Abstract
The NiII ion in the title compound, [Ni(H2PO4)2-(C10H24N4)], is six-coordinate in a distorted square bipyramidal environment. The crystal structure consists of two molecules of the title compound, each residing on a centre of inversion. Four tetramine N atoms of the macrocyclic ligand are equatorial [average Ni-N distance = 2.07 (1) A] and two O atoms, one from each dihydrogen phosphate ion, are axial [average Ni-O distance = 2.12 (3) Å]. The structure of the title complex consists of a three-dimensional framework, which delimits intersecting a-axis, b-axis and c-axis tunnels. Two types of hydrogen bonds, O-H…O and N-H…O, ensure the cohesion and stability of the molecular packing.
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream PascalFrancis, to step Corpus: 000469
- to stream PascalFrancis, to step Curation: 000598
- to stream PascalFrancis, to step Checkpoint: 000500
- to stream Main, to step Merge: 000D99
- to stream Main, to step Curation: 000D51
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Bis(dihydrogen phosphato-O)[(1SR, 4SR, -8RS, 11RS)-1,4,8,11-tetraazacyclotetradecane-κ<sup>4</sup>N]nickel(II )</title><author><name sortKey="Saoussen Namouchi Cherni" sort="Saoussen Namouchi Cherni" uniqKey="Saoussen Namouchi Cherni" last="Saoussen Namouchi Cherni">SAOUSSEN NAMOUCHI CHERNI</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1><s2>Tunis</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Tunisie</country><placeName><settlement type="city">Tunis</settlement><region nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A." last="Driss">A. Driss</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1><s2>Tunis</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Tunisie</country><placeName><settlement type="city">Tunis</settlement><region nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="El Maaoui, M" sort="El Maaoui, M" uniqKey="El Maaoui M" first="M." last="El Maaoui">M. El Maaoui</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1><s2>Tunis</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Tunisie</country><placeName><settlement type="city">Tunis</settlement><region nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">Tahar Jouini</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1><s2>Tunis</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Tunisie</country><placeName><settlement type="city">Tunis</settlement><region nuts="2">Gouvernorat de Tunis</region></placeName><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName><orgName type="university" n="3">Université de Tunis - El Manar</orgName></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">INIST</idno><idno type="inist">99-0059729</idno><date when="1998">1998</date><idno type="stanalyst">PASCAL 99-0059729 INIST</idno><idno type="RBID">Pascal:99-0059729</idno><idno type="wicri:Area/PascalFrancis/Corpus">000469</idno><idno type="wicri:Area/PascalFrancis/Curation">000598</idno><idno type="wicri:Area/PascalFrancis/Checkpoint">000500</idno><idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000500</idno><idno type="wicri:doubleKey">0108-2701:1998:Saoussen Namouchi Cherni:bis:dihydrogen:phosphato</idno><idno type="wicri:Area/Main/Merge">000D99</idno><idno type="wicri:Area/Main/Curation">000D51</idno><idno type="wicri:Area/Main/Exploration">000D51</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Bis(dihydrogen phosphato-O)[(1SR, 4SR, -8RS, 11RS)-1,4,8,11-tetraazacyclotetradecane-κ<sup>4</sup>N]nickel(II )</title><author><name sortKey="Saoussen Namouchi Cherni" sort="Saoussen Namouchi Cherni" uniqKey="Saoussen Namouchi Cherni" last="Saoussen Namouchi Cherni">SAOUSSEN NAMOUCHI CHERNI</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1><s2>Tunis</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Tunisie</country><placeName><settlement type="city">Tunis</settlement><region nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A." last="Driss">A. Driss</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1><s2>Tunis</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Tunisie</country><placeName><settlement type="city">Tunis</settlement><region nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="El Maaoui, M" sort="El Maaoui, M" uniqKey="El Maaoui M" first="M." last="El Maaoui">M. El Maaoui</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1><s2>Tunis</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Tunisie</country><placeName><settlement type="city">Tunis</settlement><region nuts="2">Gouvernorat de Tunis</region></placeName></affiliation></author><author><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">Tahar Jouini</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Département de Chimie, Faculté des Sciences, 1060 Campus Universitaire</s1><s2>Tunis</s2><s3>TUN</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>Tunisie</country><placeName><settlement type="city">Tunis</settlement><region nuts="2">Gouvernorat de Tunis</region></placeName><placeName><settlement type="city">Tunis</settlement><region type="region" nuts="2">Gouvernorat de Tunis</region></placeName><orgName type="university" n="3">Université de Tunis - El Manar</orgName></affiliation></author></analytic><series><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title><title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title><idno type="ISSN">0108-2701</idno><imprint><date when="1998">1998</date></imprint></series></biblStruct></sourceDesc><seriesStmt><title level="j" type="main">Acta crystallographica. Section C, Crystal structure communications</title><title level="j" type="abbreviated">Acta crystallogr., Sect. C Cryst. struct. commun.</title><idno type="ISSN">0108-2701</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acido complex</term><term>Analog</term><term>Crystal structure</term><term>Experimental study</term><term>Hydrogen bonds</term><term>Macrocycle</term><term>Molecular structure</term><term>Nickel II Complexes</term><term>Nitrogen crown compound</term><term>Nitrogen heterocycle</term><term>Organic ligand</term><term>Phosphato complex</term><term>XRD</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term><term>Diffraction RX</term><term>Structure cristalline</term><term>Structure moléculaire</term><term>Nickel II Complexe</term><term>Liaison hydrogène</term><term>Coordinat organique</term><term>Composé crown azote</term><term>Analogue</term><term>Hétérocycle azote</term><term>Macrocycle</term><term>Complexe aniono</term><term>Complexe phosphato</term><term>6166F</term><term>Complexe dihydrogénophosphato</term><term>1,4,8,11-Tétraazacyclotétradécane</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The Ni<sup>II</sup> ion in the title compound, [Ni(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>-(C<sub>10</sub>H<sub>24</sub>N<sub>4</sub>)], is six-coordinate in a distorted square bipyramidal environment. The crystal structure consists of two molecules of the title compound, each residing on a centre of inversion. Four tetramine N atoms of the macrocyclic ligand are equatorial [average Ni-N distance = 2.07 (1) A] and two O atoms, one from each dihydrogen phosphate ion, are axial [average Ni-O distance = 2.12 (3) Å]. The structure of the title complex consists of a three-dimensional framework, which delimits intersecting a-axis, b-axis and c-axis tunnels. Two types of hydrogen bonds, O-H…O and N-H…O, ensure the cohesion and stability of the molecular packing.</div></front></TEI><affiliations><list><country><li>Tunisie</li></country><region><li>Gouvernorat de Tunis</li></region><settlement><li>Tunis</li></settlement><orgName><li>Université de Tunis - El Manar</li></orgName></list><tree><country name="Tunisie"><region name="Gouvernorat de Tunis"><name sortKey="Saoussen Namouchi Cherni" sort="Saoussen Namouchi Cherni" uniqKey="Saoussen Namouchi Cherni" last="Saoussen Namouchi Cherni">SAOUSSEN NAMOUCHI CHERNI</name></region><name sortKey="Driss, A" sort="Driss, A" uniqKey="Driss A" first="A." last="Driss">A. Driss</name><name sortKey="El Maaoui, M" sort="El Maaoui, M" uniqKey="El Maaoui M" first="M." last="El Maaoui">M. El Maaoui</name><name sortKey="Jouini, T" sort="Jouini, T" uniqKey="Jouini T" first="T." last="Jouini">Tahar Jouini</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/NickelMaghrebV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000D51 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000D51 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Terre
|area= NickelMaghrebV1
|flux= Main
|étape= Exploration
|type= RBID
|clé= Pascal:99-0059729
|texte= Bis(dihydrogen phosphato-O)[(1SR, 4SR, -8RS, 11RS)-1,4,8,11-tetraazacyclotetradecane-κ4N]nickel(II )
}}
| This area was generated with Dilib version V0.6.27. |  |